Robert Chatfield
Bio | Education | Professional Experience | Contributions | Honors | Publications | First Author Publications | Co-Authored Publications
Staff, NASA Ames Research Center
Atmospheric Science Branch (SGG)
Business Email: robert.b.chatfield@nasa.gov
Business Phone: (650) 604-5490
Website: https://geo.arc.nasa.gov/sgg/chatfield/index.html
Bio:
Dr Robert Chatfield is the Data Analysis Lead for Methane (CH4) and Carbon Monoxide (CO), and initiated work with Lockheed Martin in 2005 demonstrating the precursor design for the GeoCarb grating mapping spectrometer as applied to CO and CH4.
For his PhD in 1982 at Colorado State University, he authored with Paul Crutzen the first publication on the large photochemical source of CO from isoprene and other plant organic emissions; they also showed how cloud-lofted dimethyl sulfide was the SO2 source of tropospheric background aerosol and how cloud-lofted peroxides (“radical reservoirs”) raise tropospheric OH radicals. Chatfield continued modeling of transport and transformation (e.g., the Subtropical Global Plume of CO from biomass burning). His focus is on mechanism, meteorological or chemical. He then turned to statistical analysis; his analysis integrates surface, airborne, and remotely sensed measurements of atmospheric species. Current work concentrates on (a) estimation of forest-burning emissions using aircraft data, (b) improved estimation of respirable particles using remote sensing data, and (c) focusing GeoCarb towards the most informative opportunities to sample XCH4 and XCO2 column quantities and quantifying sources of CH4 and other species from forest and agricultural burning.
Education:
Ph. D., Atmospheric Science, 1982
Colorado State University
Dissertation: Remote tropospheric SO2: Cloud transport of reactive sulfur emissions, with Paul J. Crutzen, Nobel Prize winner, at the Max-Planck -Institut für Chemie
M.S., Atmospheric Sciences, 1976
University of Washington
B.A., Math (Chemical Physics), 1969
Rice University
Professional Experience:
1990-Present-NASA-Ames Research Center, Moffett Field, CA
Researcher, Atmospheric Chemist
Leader of a small research group. Focus: the study of source, chemical, and transport processes where they clearly require improvement in global simulations. A recent Instrument Incubator Program award has propelled us to advocate elegant and innovative techniques for the infrared retrieval and validation of remotely sensed trace species. Basic technique: reconcile detailed, situation-specific studies of emissions and observed chemical composition (from aircraft and satellites), and deposition, and so to check the closure of chemical and particulate budgets. We use advanced statistical techniques and the NCAR Finite Volume version of Community Atmospheric Model, and our own flexible, 0-,1-,2-, or 3-dimensional models for synoptic-to-global transport and transformation for idealized or highly experiment-specific analyses. We are collaborating with other centers including Goddard Space Flight Center, University of São Paulo, University of Virginia, University of Maryland, University of North Carolina, Harvard, and others. Strong connections with those studying land use, biomass burning, surface deposition of trace species, and gaseous emissions from soils, plants, and combustion, as they compose the great global biogeochemical cycles.
1984-1990-National Center for Atmospheric Research
Postdoctoral fellow and Research Scientist
Worked on transport parametrizations, oxidant chemistry, and field observations within Atmospheric Chemistry Division.
Contributions:
Publications establish new paths of research. Here are some contributions that have had a significant impact on this field:
- Promoted robust, elegant short-wave IR measurements using satellite-borne grating mapping spectrometers as a science-focus specialist on NASA Instrument Incubator Program team.
- Interpreted remote tropospheric O3 sondes values [1977], thus demonstrating transport of Indian Ocean Brown Cloud ozone pollution to the remote Atlantic [2003].
- Conceived, analyzed and wrote a universally cited paper on a major biogenic emission, isoprene, Zimmerman, et al. [1978].
- Showed that cumulonimbus clouds had extraordinary effects on the global upper troposphere. The role of (CH3)2S a source of new aerosol there is now a commonplace.
- Demonstrated the importance of clouds in moving radical reservoirs like the peroxides which determine tropospheric cleaning power (OH radicals and O3 buildup) [1984].
- Demonstrated and estimated a simple “two-stream” model of planetary boundary layer transport that has become a standard for models that can easily treat atmospheric chemistry and physics [1987].
- Demonstrated a fundamental limitation in the simulation of the atmospheric chemistry of tropospheric ozone while also providing an origin for high smog ozone over the Equatorial Atlantic [1990]. Presented wavelet analysis pointing to a separate role for lightning [2002].
- Demonstrated a fundamental anomaly in the reactive nitrogen chemistry of the background troposphere, possibly implying “re-NOx-ification” [1995].
- Gave a quantitative mechanistic explanation for the “Great African Plume” and the “Subtropical Global Plume” describing the pollution of the Atlantic and global tropics from biomass burning [1988, 2000].
- Provided provocative evidence that aircraft NO,x plays an environmentally significant role in the troposphere above 6 km, and other sources have limited effects [1999].
Honors, Science Teams,
Scientific Societies:
Science Teams:
- NASA Instrument Incubator Program
- Global Modeling Initiative
- Global Tropospheric Experiment
- EOS Interdisciplinary Science
- Aura Validation Science Teams
- NASA Professional Development Program at NASA Headquarters, 2000–2001
- American Geophysical Union, Annual Invited Lecturer at University of California at Berkeley
Publications:
(See web page (URL above) for recent presentations and papers in PDF format.)
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Chatfield, R., H. Guan, A.M. Thompson, and H. Smit, Mechanisms for the Intraseasonal Variability of Tropospheric Ozone over the Indian Ocean during the Winter Monsoon. Submitted to J. Geophys. Res., 2006JD007347, 2006.
Chatfield, R. B., H. Guan, A. M. Thompson, and J. Witte. 2004. Convective Lofting Links Indian Ocean Air Pollution to Paradoxical South Atlantic Ozone Maxima. Geophys. Res. Lett., 31, L06103, doi:10.1029/2003GL018866.
Chatfield R. B., Z. Guo, G. W. Sachse, D. R. Blake, and N. J. Blake. 2002. The subtropical global plume in the Pacific Exploratory Mission-Tropics A (PEM-Tropics A), PEM-Tropics B, and the Global Atmospheric Sampling Program (GASP): How tropical emissions affect the remote Pacific. J. Geophys. Res., 107 (D16), doi:10.1029/2001JD000497.
Folkins, I., and R.B. Chatfield. 2000. Impact of acetone on ozone production and OH in the upper troposphere at high NO. J. Geophys. Res., 105,11,585–11,599.
Chatfield, R. B. 2000. “Atmospheric Composition and Structure” and “Atmospheric Motions and the Greenhouse Effect.” In Earth System Science: Processes and Issues, G. Ernst, ed. Cambridge: Cambridge University Press.
Chatfield, R. B., J. A. Vastano, L. Li, G. W. Sachse, and V.S. Connors. 1998. The Great African Plume from biomass burning: A three-dimensional study of Trace-A carbon monoxide. J. Geophysical Res., 103, 28,059-28,077.
Chatfield, R. B., J. A. Vastano, H. B. Singh, and G.W. Sachse. 1996. A generalized model of how fire emissions and chemistry produce African / oceanic plumes (O3, CO, PAN, smoke) seen in Trace-A. J. Geophysical Res, 101, 24,279–24,306.
Chatfield, R. B. 1994. Anomalous HNO3/NOx ratio of remote tropospheric air: Conversion of nitric acid to formic acid and NOx? Geophys. Res. Lett., 21, 2705–2708.
Chatfield, R. B., and A. C. Delany. 1990. Convection links biomass burning to increased tropical ozone: However, models will tend to overpredict O3. J. Geophysical Res., 95, 18473–18488.
Chatfield, R. B., and P. J. Crutzen 1990. Are there interactions of iodine and sulfur species in marine air photochemistry? J. Geophysical Res., 95, 22319–22341.
Ferek, R. J., R. B. Chatfield, and M. O. Andreae. 1986. Vertical distribution of dimethylsulfide in the ma-rine atmosphere: implications for the atmospheric sulfur cycle. Nature, 320, 514–516.
Chatfield, R. B. and P. J. Crutzen. 1984. Sulfur dioxide in remote oceanic air: Cloud transport of reactive precursors, J. Geophys. Res., 89, 7111–7132.
Zimmerman, P. R., R. B. Chatfield, J. Fishman, P. J. Crutzen, and P. L. Hanst. 1978. Estimates of the production of CO and H2 from the oxidation of hydrocarbon emissions from vegetation. Geophys. Res. Lett., 5, 679–682.
- Chatfield, R., and R. F. Esswein (2014), True Emission Factors for Western Forest Fires: Better Estimation and Usage, Long Beach, California, Proceedings of A&WMA’s 107th Annual Conference, 107, 27-31.
- Chatfield, R., et al. (2013), Ozone Monitoring Instrument (OMI) multi satellite observations, Iss., 63, 1434-1446.
- Chatfield, R., and R. Esswein (2012), R. Esswein.. Estimation of surface O3 from lower-troposphere partial-column information, Atmos. Environ., 61, 103-113.
- Chatfield, R., et al. (2010), Controls on urban ozone production rate as indicated by formaldehyde oxidation rate and nitric oxide, Atmos. Environ., 44, 5395-5406, doi:10.1016/j.atmosenv.2010.08.056.
- Chatfield, R., et al. (2007), Mechanisms for the intraseasonal variability of tropospheric ozone over the Indian Ocean during the winter monsoon, J. Geophys. Res., 112, D10303, doi:10.1029/2006JD007347.
- Chatfield, R., et al. (2004), Convective lofting links Indian Ocean air pollution to paradoxical South Atlantic ozone maxima, Geophys. Res. Lett., 31, L06103, doi:10.1029/2003GL018866.
- Chatfield, R., et al. (2002), The subtropical global plume in the Pacific Exploratory Mission-Tropics A (PEM-Tropics A), PEM-Tropics B, and the Global Atmospheric Sampling Program (GASP): How tropical emissions affect the remote Pacific, J. Geophys. Res., 107, doi:10.1029/2001JD000497.
- Chatfield, R., et al. (1996), A general model of fire emissions and chemistry African/oceanic plumes (O3, CO, PAN, smoke) in TRACE A, J. Geophys. Res., 101.D19, 24,279-24.
- Chatfield, R. (1994), The Anomalous HNO3/NOx Ratio of Remote Tropospheric Air: Conversion of Nitric Acid to Formic Acid and NOx?”, Geophys. Res. Lett., 21, 2705-2708.
- Chatfield, R., and P. J. Crutzen (1990), Are There Interactions of Iodine and Sulfur Species in Marine Air Photochemistry?, J. Geophys. Res., D13, 22,319-22.
- Chatfield, R., and A. C. Delany (1990), Convection Links Biomass Burning to Increased Tropical Ozone: However, Models will tend to Overpredict O3, J. Geophys. Res., D11, 18.
- Lee, H. J., R. Chatfield, and A. Strawa (2016), Enhancing the Applicability of Satellite Remote Sensing for PM2.5 Estimation Using MODIS Deep Blue AOD and Land Use Regression in California, United States. Environmental Science & Technology, 50, 6546-6555, doi:10.1021/acs.est.6b01438.
- Sorek-Hamer, M., et al. (2013), Improved retrieval of PM2.5 from satellite data products using non-linear methods, Environmental Pollution, 182, 417-423.
- Natraj, V., et al. (2011), Multi-spectral sensitivity studies for the retrieval of tropospheric and lowermost tropospheric ozone from simulated clear-sky GEO-CAPE measurements, Atmos. Environ., 45, 7151-7165, doi:10.1016/j.atmosenv.2011.09.014.
- Freitas, S. R., et al. (2009), The Coupled Aerosol and Tracer Transport model to the Brazilian developments on the Regional Atmospheric Modeling System (CATT-BRAMS) – Part 1: Model description and evaluation, Atmos. Chem. Phys., 9, 2843-2861.
- Frietas, S. R., et al. (2007), Including the sub-grid scale plume rise of vegetation fires in low resolution atmospheric transport models, Atmos. Chem. Phys., 7, 3385-3398.
- Guan, H., et al. (2007), Modeling the effect of plume-rise on the transport of carbon monoxide over Africa and its exports with NCAR CAM, Atmos. Chem. Phys. Discuss., 7, 18145-18177.
- Thompson, A. M., et al. (2007), Intercontinental Chemical Transport Experiment Ozonesonde Network Study (IONS) 2004: 1. Summertime upper troposphere/lower stratosphere ozone over northeastern North America, J. Geophys. Res., 112, D12S12, doi:10.1029/2006JD007441.
- Liu, X., et al. (2006), First directly retrieved global distribution of tropospheric column ozone from GOME: Comparison with the GEOS-CHEM model, J. Geophys. Res., 111, D02308, doi:10.1029/2005JD006564.
- Freitas, S., et al. (2005), Monitoring the transport of biomass burning emissions in South America, Environmental Fluid Mechanics, 5, 135-167.
- Singh, H., et al. (2004), Analysis of the atmospheric distribution, sources, and sinks of oxygenated volatile organic chemicals (OVOC) based on measurements over the Pacific during TRACE-P, J. Geophys. Res., 109, doi:10.1029/2003JD003883.
- Faloona, I., et al. (2000), Observations of HOX and its relationship with NOX in the upper troposphere during SONEX, J. Geophys. Res., 105, 3771-3783.
- Folkins, I., and R. Chatfield (2000), Impact of acetone on ozone production and OH in the upper troposphere at high NOx, J. Geophys. Res., 105, 11,585-11.
- Folkins, I., et al. (1997), Biomass burning and deep convectionin Indonesia: results from ASHOE/MESA, J. Geophys. Res., 102, 13,291-13.
- Olson, J., et al. (1997), Results from theIPCC photchemical model intercomparison (PhotoComp), J. Geophys. Res., 102, 5979-5991.
- Krishnamurti, T. N., et al. (1996), Passive tracer transports relevant to the TRACE-A Experiment, J. Geophys. Res., 101, 23,889-23.
- Potter, C., S. Klooster, and R. Chatfield (1996), Production and consumption of carbon monoxide in soils: A global model analysis of spatial and seasonal variation, Chemosphere, 33.6, 1175-1193.
- Singh, H., et al. (1996), Impact of biomass burning emissions on the composition of the south Atlantic troposphere: Reactive nitrogen and ozone, J. Geophys. Res., 101.D19, 24,203-24.
- Ridley, B., et al. (1992), Measurements and Model Simulations of the Photostationary State During the Mauna Loa Observatory Photochemistry Experiment: Implications for Radical Concentrations and Ozone Production and Loss Rates, J. Geophys. Res., 97, 10,375-10.
- Madronich, S., et al. (1990), A Photochemical Origin of Acetic Acid in the Troposphere, Geophys. Res. Lett., 17, 2361-2364.