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Binary Colloidal Alloy Test - 5: Three-Dimensional Melt (BCAT-5-3D-Melt)
12.05.12

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Overview | Description | Applications | Operations | Results | Publications | Imagery

Experiment Overview

This content was provided by Arjun Yodh, Ph.D., and is maintained in a database by the ISS Program Science Office.

Brief Summary

In Binary Colloidal Alloy Test - 5: Three-Dimensional Melt (BCAT-5-3D-Melt), crewmembers photograph specially designed microscopic particles (colloids) suspended in a liquid over a period of time. The particles are designed to melt when temperatures warm above 23C (when the station is warmed by sun) and crystallize when the temperatures drop below 23C (when the Earth blocks the sun). The results help scientists develop fundamental physics concepts which are important in developing next generation technologies in computers and advanced optics.

Principal Investigator(s)

  • Arjun Yodh, Ph.D., University of Pennsylvania, University Park, PA, United States
  • Co-Investigator(s)/Collaborator(s)

    Information Pending

    Developer(s)

    ZIN Technologies Incorporated, Cleveland, OH, United States

    Sponsoring Space Agency

    National Aeronautics and Space Administration (NASA)

    Sponsoring Organization

    Human Exploration and Operations Mission Directorate (HEOMD)

    ISS Expedition Duration:

    March 2009 - October 2013



    Expeditions Assigned

    19/20,21/22,25/26,27/28,29/30,31/32,33/34,35/36

    Previous ISS Missions

    The predecessors to BCAT-5, BCAT-3 and BCAT-4 are in operation on the ISS.

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    Experiment Description

    Research Overview

    • The Binary Colloidal Alloy Test - 5: Three-Dimensional Melt (BCAT-5-3D-Melt) takes advantage of the microgravity environment on the ISS to allow the liquid suspended particles to crystallize and melt without the interference of gravitational forces which can alter the nature of these processes.


    • The particles are designed to melt when temperatures warm above 23C (when the station is warmed by sun) and to crystallize when the temperatures drop below 23C (when the Earth blocks the sun).


    • This work provides the opportunity to observe how order arises out of disorder in nature. An astronaut thoroughly mixes the samples to assure that they are disordered. Afterwards, nature introduces order to the sample by crystallizing it. This does not happen on Earth with these types of samples because gravity interferes with this natural process.


    • The nature of crystallization is beginning to be better understood thanks to these microgravity experiments. While the patterns that atoms, molecules, and particles make when they crystallize are often hard to predict, the knowledge gained from BCAT-5-3D-Melt aims improves their predictability.


    • Understanding how to make control crystallization and the order of the atoms, molecules, and particles in crystals leads to a wide variety of next generation technologies from computers and advanced optics to new medicines.

    Description

    The Binary Colloidal Alloy Test - 5 (BCAT-5) hardware supports four investigations. Samples 1 - 5, the Binary Colloidal Alloy Test - 5: Phase Separation (BCAT-5-PhaseSep) will study collapse (phase separation rates that impact product shelf-life). In microgravity the physics of collapse is not masked by being reduced to a simple top and bottom phase as it is on Earth. Samples 6 - 8, Binary Colloidal Alloy Test - 5: Compete (BCAT-5-Compete) will study the competition between phase separation and crystallization, which is important in the manufacture of plastics and other materials. Sample 9, Binary Colloidal Alloy Test - 5: Seeded Growth (BCAT-5-SeededGrowth) will study the properties of concentrated systems of small particles when 99.8% are identical 0.36 diameter micron spheres and 0.2% are 4.14 microns in diameter (11.5x larger); these seed particles may cause heterogeneous crystal growth. Sample 10, Binary Colloidal Alloy Test - 5: Three-Dimensional Melt (BCAT-5-3D-Melt) will look at the mechanisms of crystal formation and 3-dimensional melting using colloidal particles that change size with temperature.

    The BCAT-5-3D-Melt sample will consist of a monodisperse nearly-hard-sphere colloidal suspension near its crystallization point. For this investigation small temperature changes that change the particle volume fraction will move the equilibrium system towards and away from the melting transition. The key ingredient in these samples is a thermosensitive polymer, poly(N-isopropylacrylamide (NIPA); the temperature-sensitive character of the samples stems from the temperature dependent solubility of NIPA polymer in water. Below its theta temperature (the temperature at which the coiled polymer molecules expand to their full contour lengths and become rod-shaped) of approximately 31 degrees C, water is a good solvent and NIPA polymer assumes a swollen coil form; in this regime a small increase of temperature increases monomer-monomer attractions and thus the size of the isolated polymer decreases. Above the theta temperature, water is a poor solvent and NIPA has a collapsed globule form.

    The BCAT-5-3D-Melt experiment will simply record sample temperature and observe (by photography) whether the sample crystallizes, noting at what temperature the sample experiences the fluid-solid transition. This information will be also be useful for future experiments planned for ISS.

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    Applications

    Space Applications

    BCAT-5 will ultimately impact our understanding of the strength and thermal conductivity of materials by providing insight into the effects of size variation in dense suspensions of particles. For example, the careful selection of crystallization promoters for controlling the crystallite size and size distribution may lead to improvement in materials fabrication processes. The suppression of crystal nucleation in polydisperse colloids has important implications for the morphology of polycrystalline materials.

    Earth Applications

    BCAT-5 will evolve the field of colloidal engineering, which creates materials with novel properties using colloidal particles as precursors. To piece together answers to the scientific puzzles being studied, BCAT-5 takes advantage of the microgravity environment on the ISS to prevent the colloidal particles in these samples from encountering sedimentation, convection, and gravitational jamming.

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    Operations

    Operational Requirements

    The BCAT-5 experiment consists of ten small samples of colloidal particles. The ten BCAT-5 samples are contained within a small case the size of a school textbook. The experiment requires a crewmember to set up on the Maintenance Work Area (MWA) or on a handrail/seat track configuration. Initially the sample will require manual photographs to be downlinked by an astronaut to investigators on the ground for analysis. Following configuration confirmation from investigators the automated EarthKAM software will be setup to take digital photographs of samples at close range using the onboard Kodak DCS760 camera. Camera Control Files for running the EarthKAM software can be uploaded from Earth to control the photography intervals (how many photographs per hour and for how many days) once it is running. The pictures are downlinked to investigators on the ground for analysis.

    Operational Protocols

    A crewmember sets up the video camera and BCAT-5 hardware (Slow Growth Sample Module, DCS760 Camera, pen-light source, flash and SSC Laptop with EarthKAM software) in the Maintenance Work Area (MWA) to document the BCAT-5 operations as performed on-board the ISS. The crewmember homogenizes (mixes) the sample(s) and takes the first photographs manually. This helps them optimize the setup and shows that the samples were initially fully homogenized when publishing results later. The EarthKAM software automates the rest of the photography session over a period of days to a few weeks. The crewmember performs a daily status check once a day (when time is available) to assure proper alignment and focus. At the completion of the run, the crewmember tears down and stows all hardware.

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    Results/More Information

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    Related Websites
  • Binary Colloidal Alloy Test - 3 (BCAT-3)
  • NIH BioMed-ISS Meeting, 2009BCAT-5-3D-Melt
  • NIH BioMed-ISS Meeting Video Presentation, 2009BCAT-5-3D-Melt
  • ISS Research Project-BCAT-5-3D-Melt
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    Imagery

    image NASA Image: ISS016E027863 - Astronaut Dan Tani photographing the BCAT-3 Sample Module using his own design for a ceiling mount in Node 2 of the International Space Station. Great high contrast pictures of difficult-to-capture images resulted from using this setup (February 2008).
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    image NASA Image: ISS025E008239 - NASA astronaut Shannon Walker, Expedition 25 flight engineer, uses a digital still camera to photograph Binary Colloidal Alloy Test-5 (BCAT-5) experiment samples in the Kibo laboratory of the International Space Station.
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    Information provided by the investigation team to the ISS Program Scientist's Office.
    If updates are needed to the summary please contact JSC-ISS-Program-Science-Group. For other general questions regarding space station research and technology, please feel free to call our help line at 281-244-6187 or e-mail at JSC-ISS-Payloads-Helpline.