Binary Colloidal Alloy Test - 6 - Colloidal Disks (BCAT-6-Colloidal Disks) - 07.14.16
The Binary Colloidal Alloy Test 6: Colloidal Disks (BCAT-6-Colloidal Disks) experiments use liquids containing microscopic suspended particles, known as colloids, as models for studying liquid crystals. The use of unevenly shaped particles clumped together into colloidal disks should produce a new phase, which has been predicted but never before seen. It is important to fully understand the properties of liquid crystals since they are widely used in televisions, computers, cell phones and much more. Science Results for Everyone
Information Pending Experiment Details
Arjun Yodh, Ph.D., University of Pennsylvania, Philadelphia, PA, United States
Peter Yunker, Ph.D., University of Pennsylvania, Philadelphia, PA, United States
Zexin Zhang, Ph.D., University of Pennsylvania, Philadelphia, PA, United States
ZIN Technologies Incorporated, Cleveland, OH, United States
Sponsoring Space Agency
National Aeronautics and Space Administration (NASA)
Human Exploration and Operations Mission Directorate (HEOMD)
ISS Expedition Duration
September 2010 - September 2013
The BCAT predecessors; BCAT-3 operated on ISS, and BCAT, operated on Mir in 1997 and 1998. BCAT-4 launched March 11, 2008 on 1J/A, and BCAT-5 launched June 13, 2009 on 2J/A.
- Sun glasses that contain polarizing lenses allow one type of light through (vertically polarized light) and block the other type of light (horizontally polarized light). The type of light that is blocked is the type most often reflected off of car bumpers, windshields, and the like. Liquid crystals can change one type of polarization into another and by doing so can either block or allow light to go through a display like those used in iPods and iPhones.
- The Binary Colloidal Alloy Test-6 (BCAT-6), colloidal disks experiment tests the organization of the molecular constituents of a new type of liquid crystal capable of rotating the polarization of light.
- The experiments relate to applications in the design of nanomaterials, new leading edge materials designed with molecular precision at the nanoscale.
Scientists at the University of Pennsylvania have two samples which consist of suspensions of colloidal disks. Colloidal disks in suspension behave in fundamentally different ways than their spherical analogs studied in other parts of BCAT. Colloidal disks self-assemble like liquid crystals, forming, for example, aligned (nematic) phases and columnar phases depending on sample volume fraction and disk thickness-to-diameter ratio. It is anticipated that the finite disk size and shape in the samples leads to even more interesting entropic (i.e. excluded volume driven) phase behavior in microgravity. In particular, calculations and simulations have clearly predicted the formation of a stable cubatic phase at relatively high volume fraction (i.e. ~0.5) for disk thickness-to-diameter ratios between 0.15 and 0.30. In this case the system is predicted to evolve from the one phase to another as a function of increasing volume fraction for a fixed thickness-to-diameter ratio. An aligned nematic phase has not been observed by the theorists in this regime.
BCAT experiments lay a foundation for studying even smaller particles, known as nanoparticles, and nanoparticle systems in microgravity. The research increases our understanding of special liquid crystals that can change the direction of light, which could improve space-based technology such as astronaut helmets.
Colloidal disks form in a very similar manner as liquid crystals do, and point a certain way depending on factors like density and size. The experiments use the disks as a model to study a new type of liquid crystal which can rotate light. By doing this, liquid crystal displays could block or pass light through a display, such as those used in cell phones and tablets. The use of unevenly shaped (asymmetric) particles could produce crystals that grow in a specific direction, which could be used to develop tunable crystals.
Operational Requirements and Protocols
The current plan for this experiment is to conduct it over a 7 or 14-day session, each of which can be run incrementally and require about 7 hours of crew time; a third session to mix and photograph all 10 samples (about 4.6 hours of crew time) and then a fourth session at six months to photograph all ten samples which is slotted to take about four hours of crew time. As such, new information will undoubtedly be learned, and the nature of the experiments conducted will evolve to take advantage of this new information.
Session 1: Set up hardware, take baseline photos of all ten samples; homogenize samples 6-10 then samples 9 and 10, then automatically photograph sample 1 (using EarthKAM software on laptop) every hour for 7 days. Perform sample 1 daily status check each day. After seven-day run, perform crystal search/photography on 6-10. Homogenize sample 2, automatically photograph sample 2 (using EarthKAM software on laptop) every hour for 7 days. Perform sample 1 daily status check each day. After seven-day run, perform crystal search/photography on 6-10. If necessary, tear down after operations are complete but keeping setup intact is preferred to save crew time.
Session 2: Set up hardware, homogenize samples 3, 4 and 5 one at a time then automatically photograph each sample (using EarthKAM software on laptop) every hour for 14 days each. Perform Crystal Check and Photography procedures on 6-10 if crystals not found/photographed in Session 1. If necessary, tear down after operations are complete but keeping setup intact is preferred to save crew time. .
Session 3: Homogenize and photograph samples 1-10 (using EarthKAM software on laptop) and stow sample module for six months. The experiment is torn down after operations are complete. .
Session 4: At six months after homogenization, manually photograph Ssamples 1 through 10. Re-stow sample module and tear down after operations are complete.
Decadal Survey Recommendations
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ISS Research Project-BCAT-Colloidal-Disks
NIH BioMed-ISS Meeting Video Presentation, 2009-BCAT-6-Colloidal_Disks
NIH BioMed-ISS Meeting, 2009-BCAT-6-Colloidal_Disks
BCAT-6 - Colloidal Disks Samples 9 and 10. Sample 9 shows a thickness to diameter ratio: 0.20 volume fraction: approx. 10% (volume by weight). Sample 10 shows a thickness to diameter ratio: 0.20 volume fraction: approx. 50% (volume by weight).
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